Subject: 84(4) : Another Derivation of the RFR Chemical Shift
Date: Sun, 29 Apr 2007 04:59:18 EDT
This is another derivation of the RFR chemical shift which uses a root mean sqaure hamiltonian and a pump beam wave form of the type sketched in Fig. (1). This wave form would be synthesized electronically using radio frequency apparatus. The pump beam also has to be circularly poalrized. The resulting RFR spectrum has the following major advantages:
1) Greatly increased resolution over ESR and NMR. 2) Site specific chemical shifts giving a spectrum. 3) No need for magnets. 4) Resolved fine and hyperfine structure because of the increased spacing between chemically shifted lines.
The calculation is entirely classical in the SU(2) basis. A probe beam photon (e.g. of an infra red interferometer) is absorbed between the two energy levels of the interaction hamiltonian given in eqs. (14) and (15).
Attachment: a84thpapernotes4.pdf